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176

Yb

a

176

Lu

a

178

Hf

180

Hf Sig

Hf

b 176

Hf

176

Hf

d

“ ı

c

T

DM

e

age

f

177

Hf

177

Hf

177

Hf

177

Hf

(V)

177

Hf

177

Hf

(t)

İ+I (Ga) (Ma)

İ+I

(t)

d

Grain

“ ı

“ ı

±2ı

c

Sequence 1

Plesovice 26_2

0.0050 4 0.

00012 1 1.46710 1

.88640 7 0.282457 24 0.282456 -4.1 0.9 1.25 338

Plesovice 32_1

0.0042 3 0.

00010 1 1.46721 1

.88669 13 0.282461 23 0.282460 -4.0 0.8 1.24 338

Plesovice 40_6

0

.0061 5 0.00014 1 1

.46720 1.88676 16 0.282469 26 0.282468 -3.7 0.9 1.23 338

Plesovice 40_7

0

.0062 5 0.00014 1 1

.46715 1.88667 16 0.282462 18 0.282461 -3.9 0.6 1.24 338

Plesovice 40_8

0

.0062 5 0.00013 1 1

.46716 1.88672 15 0.282444 20 0.282443 -4.6 0.7 1.28 338

Plesovice 40_9

0

.0061 5 0.00013 1 1

.46714 1.88675 14 0.282449 23 0.282448 -4.4 0.8 1.27 338

Plesovice 40_10

0

.0077 6 0.00017 1

1.46712 1.88652 13 0.282454 22 0.282453 -4.2 0.8 1.26 338

Plesovice 48_4

0

.0064 5 0.00015 1 1

.46718 1.88682 26 0.282465 15 0.282464 -3.8 0.5 1.24 338

Plesovice 48_5

0

.0065 5 0.00015 1 1

.46717 1.88682 26 0.282455 17 0.282454 -4.2 0.6 1.26 338

Sequence 2

Plesovice_40_90_1

0

.0073 6 0.00017 1

1.46716 1.88668 13 0.282478 20 0.282477 -3.4 0.7 1.21 338

Plesovice_40_90_2

0

.0076 6 0.00017 1

1.46720 1.88659 12 0.282456 22 0.282455 -4.2 0.8 1.25 338

Plesovice_40_90_3

0.0035 3 0.00008 0 1.46718 1.88672 12 0.282464 23 0.282463 -3.9 0.8 1.24 338

Plesovice_40_90_4

0.0059 5 0.

00014 1 1.46718 1

.88675 13 0.282460 17 0.282459 -4.0 0.6 1.25 338

Plesovice_40_90_5

0

.0053 4 0.00013 1 1

.46721 1.88667 12 0.282450 21 0.282449 -4.4 0.8 1.26 338

Sequence 3

Plesovice_40-5-90_1

0.0037 3 0.00008 1 1.46718 1.88673 15 0.282470 23 0.282469 -3.6 0.8 1.23 338

Plesovice_40-5-90_2

0

.0046 4 0.00011 1 1

.46717 1.88670 11 0.282452 31 0.282452 -4.3 1.1 1.26 338

Plesovice_40-5-90_3

0

.0060 5 0.00015 1 1

.46725 1.88682 14 0.282463 28 0.282462 -3.9 1.0 1.24 338

Plesovice_40-5-90_4

0.0035 3 0.00008 0 1.46713 1.88687 14 0.282466 24 0.282465 -3.8 0.9 1.23 338

Plesovice_40-5-90_5

0.0025 2 0.00006 0 1.46723 1.88694 14 0.282480 25 0.282480 -3.3 0.9 1.20 338

Plesovice_40-5-90_6

0

.0057 5 0.00013 1 1

.46727 1.88698 13 0.282515 29 0.282514 -2.1 1.0 1.14 338

Plesovice_40-5-90_7

0.0038 3 0.00009 1 1.46717 1.88670 13 0.282442 22 0.282441 -4.6 0.8 1.28 338

Sequence 6

Plesov-50-100-6_10

0

.0058 5 0.00014 1 1

.46719 1.88673 14 0.282455 22 0.282454 -4.2 0.8 1.25 338

Plesov-50-100-6_9

0

.0063 5 0.00015 1 1

.46718 1.88688 13 0.282436 16 0.282435 -4.9 0.6 1.29 338

Plesov-50-100-6_8

0.0059 5 0.

00014 1 1.46710 1

.88670 14 0.282468 17 0.282467 -3.7 0.6 1.23 338

Plesov-50-100-6_7

0

.0063 5 0.00015 1 1

.46711 1.88678 14 0.282442 18 0.282441 -4.7 0.6 1.28 338

Plesov-50-100-6_6

0

.0064 5 0.00016 1 1

.46716 1.88663 14 0.282463 19 0.282462 -3.9 0.7 1.24 338

Plesov-50-100-6_5

0

.0061 5 0.00015 1 1

.46716 1.88678 14 0.282463 18 0.282462 -3.9 0.6 1.24 338

Plesov-50-100-6_4

0

.0062 5 0.00016 1 1

.46711 1.88671 14 0.282445 16 0.282444 -4.6 0.6 1.28 338

Plesov-50-100-6_3

0

.0062 5 0.00015 1 1

.46716 1.88669 14 0.282467 17 0.282466 -3.8 0.6 1.23 338

Plesov-50-100-6_1

0

.0064 5 0.00016 1 1

.46715 1.88678 14 0.282452 21 0.282451 -4.3 0.8 1.26 338

Quoted uncertainties (absolute) relate to the last quoted figure. The effect of the inter-element fractionation on Lu/Hf was estimated to be

about 6 % or less based on analyses of the GJ-1 and WůĞƐŽǀŝēĞ zircon. Accuracy and reproducibility was checked by repeated analyses of

reference zircon GJ-1 and WůĞƐŽǀŝēĞ (data given as mean with 2 standard deviation uncertainties).

(a)

176

Yb/

177

Hf = (

176

Yb/

173

Yb)

true

x (

173

Yb/

177

Hf)

meas

x (M

173(Yb)

/M

177(Hf)

)

ɴ;,ĨͿ

, ɴ;,ĨͿ = ln((

179

Hf/

177

Hf

true

)/(

179

Hf/

177

Hf

measured

)) / ln(M

179(Hf)

/M

177(Hf)

), M

= mass of respective isotopes. The

176

Lu/

177

Hf was calculated in a similar way using

175

Lu/

177

Hf and ɴ;zďͿ.

(b)

Mean Hf signal in volts.

(c)

Uncertainties are quadratic additions of the within-run precision and the daily reproducibility of the 40ppb-JMC475 solution. Uncertainties

for the JMC475 quoted at 2SD (2 standard deviation).

(d)

Initial

176

Hf/

177

Hf and ɸ,Ĩ calculated using the apparent U-Pb age determined by LA-ICP-MS dating (see column f), and the CHUR

parameters:

176

Lu/

177

Hf = 0.0336, and

176

Hf/

177

Hf = 0.282785 (Bouvier et al. 2008).

(e)

Two stage model age in Ga using measured

176

Lu/

177

Lu of each spot (first stage = age of zircon), a value of 0.0113 for the average

continental crust (second stage, values compiled from Rudnick and Gao (2003), and depleted mantle

176

Lu/

177

Lu = 0.0379, and

176

Hf/

177

Hf =

0.283164.

(f)

Apparent U-Pb age determined by LA-ICP-MS.

335