176
Yb
a
176
Lu
a
178
Hf
180
Hf Sig
Hf
b 176
Hf
176
Hf
d
ı
c
T
DM
e
age
f
177
Hf
177
Hf
177
Hf
177
Hf
(V)
177
Hf
177
Hf
(t)
İ+I (Ga) (Ma)
İ+I
(t)
d
Grain
ı
ı
±2ı
c
Sequence 1
Plesovice 26_2
0.0050 4 0.
00012 1 1.46710 1
.88640 7 0.282457 24 0.282456 -4.1 0.9 1.25 338
Plesovice 32_1
0.0042 3 0.
00010 1 1.46721 1
.88669 13 0.282461 23 0.282460 -4.0 0.8 1.24 338
Plesovice 40_6
0
.0061 5 0.00014 1 1
.46720 1.88676 16 0.282469 26 0.282468 -3.7 0.9 1.23 338
Plesovice 40_7
0
.0062 5 0.00014 1 1
.46715 1.88667 16 0.282462 18 0.282461 -3.9 0.6 1.24 338
Plesovice 40_8
0
.0062 5 0.00013 1 1
.46716 1.88672 15 0.282444 20 0.282443 -4.6 0.7 1.28 338
Plesovice 40_9
0
.0061 5 0.00013 1 1
.46714 1.88675 14 0.282449 23 0.282448 -4.4 0.8 1.27 338
Plesovice 40_10
0
.0077 6 0.00017 1
1.46712 1.88652 13 0.282454 22 0.282453 -4.2 0.8 1.26 338
Plesovice 48_4
0
.0064 5 0.00015 1 1
.46718 1.88682 26 0.282465 15 0.282464 -3.8 0.5 1.24 338
Plesovice 48_5
0
.0065 5 0.00015 1 1
.46717 1.88682 26 0.282455 17 0.282454 -4.2 0.6 1.26 338
Sequence 2
Plesovice_40_90_1
0
.0073 6 0.00017 1
1.46716 1.88668 13 0.282478 20 0.282477 -3.4 0.7 1.21 338
Plesovice_40_90_2
0
.0076 6 0.00017 1
1.46720 1.88659 12 0.282456 22 0.282455 -4.2 0.8 1.25 338
Plesovice_40_90_3
0.0035 3 0.00008 0 1.46718 1.88672 12 0.282464 23 0.282463 -3.9 0.8 1.24 338
Plesovice_40_90_4
0.0059 5 0.
00014 1 1.46718 1
.88675 13 0.282460 17 0.282459 -4.0 0.6 1.25 338
Plesovice_40_90_5
0
.0053 4 0.00013 1 1
.46721 1.88667 12 0.282450 21 0.282449 -4.4 0.8 1.26 338
Sequence 3
Plesovice_40-5-90_1
0.0037 3 0.00008 1 1.46718 1.88673 15 0.282470 23 0.282469 -3.6 0.8 1.23 338
Plesovice_40-5-90_2
0
.0046 4 0.00011 1 1
.46717 1.88670 11 0.282452 31 0.282452 -4.3 1.1 1.26 338
Plesovice_40-5-90_3
0
.0060 5 0.00015 1 1
.46725 1.88682 14 0.282463 28 0.282462 -3.9 1.0 1.24 338
Plesovice_40-5-90_4
0.0035 3 0.00008 0 1.46713 1.88687 14 0.282466 24 0.282465 -3.8 0.9 1.23 338
Plesovice_40-5-90_5
0.0025 2 0.00006 0 1.46723 1.88694 14 0.282480 25 0.282480 -3.3 0.9 1.20 338
Plesovice_40-5-90_6
0
.0057 5 0.00013 1 1
.46727 1.88698 13 0.282515 29 0.282514 -2.1 1.0 1.14 338
Plesovice_40-5-90_7
0.0038 3 0.00009 1 1.46717 1.88670 13 0.282442 22 0.282441 -4.6 0.8 1.28 338
Sequence 6
Plesov-50-100-6_10
0
.0058 5 0.00014 1 1
.46719 1.88673 14 0.282455 22 0.282454 -4.2 0.8 1.25 338
Plesov-50-100-6_9
0
.0063 5 0.00015 1 1
.46718 1.88688 13 0.282436 16 0.282435 -4.9 0.6 1.29 338
Plesov-50-100-6_8
0.0059 5 0.
00014 1 1.46710 1
.88670 14 0.282468 17 0.282467 -3.7 0.6 1.23 338
Plesov-50-100-6_7
0
.0063 5 0.00015 1 1
.46711 1.88678 14 0.282442 18 0.282441 -4.7 0.6 1.28 338
Plesov-50-100-6_6
0
.0064 5 0.00016 1 1
.46716 1.88663 14 0.282463 19 0.282462 -3.9 0.7 1.24 338
Plesov-50-100-6_5
0
.0061 5 0.00015 1 1
.46716 1.88678 14 0.282463 18 0.282462 -3.9 0.6 1.24 338
Plesov-50-100-6_4
0
.0062 5 0.00016 1 1
.46711 1.88671 14 0.282445 16 0.282444 -4.6 0.6 1.28 338
Plesov-50-100-6_3
0
.0062 5 0.00015 1 1
.46716 1.88669 14 0.282467 17 0.282466 -3.8 0.6 1.23 338
Plesov-50-100-6_1
0
.0064 5 0.00016 1 1
.46715 1.88678 14 0.282452 21 0.282451 -4.3 0.8 1.26 338
Quoted uncertainties (absolute) relate to the last quoted figure. The effect of the inter-element fractionation on Lu/Hf was estimated to be
about 6 % or less based on analyses of the GJ-1 and WůĞƐŽǀŝēĞ zircon. Accuracy and reproducibility was checked by repeated analyses of
reference zircon GJ-1 and WůĞƐŽǀŝēĞ (data given as mean with 2 standard deviation uncertainties).
(a)
176
Yb/
177
Hf = (
176
Yb/
173
Yb)
true
x (
173
Yb/
177
Hf)
meas
x (M
173(Yb)
/M
177(Hf)
)
ɴ;,ĨͿ
, ɴ;,ĨͿ = ln((
179
Hf/
177
Hf
true
)/(
179
Hf/
177
Hf
measured
)) / ln(M
179(Hf)
/M
177(Hf)
), M
= mass of respective isotopes. The
176
Lu/
177
Hf was calculated in a similar way using
175
Lu/
177
Hf and ɴ;zďͿ.
(b)
Mean Hf signal in volts.
(c)
Uncertainties are quadratic additions of the within-run precision and the daily reproducibility of the 40ppb-JMC475 solution. Uncertainties
for the JMC475 quoted at 2SD (2 standard deviation).
(d)
Initial
176
Hf/
177
Hf and ɸ,Ĩ calculated using the apparent U-Pb age determined by LA-ICP-MS dating (see column f), and the CHUR
parameters:
176
Lu/
177
Hf = 0.0336, and
176
Hf/
177
Hf = 0.282785 (Bouvier et al. 2008).
(e)
Two stage model age in Ga using measured
176
Lu/
177
Lu of each spot (first stage = age of zircon), a value of 0.0113 for the average
continental crust (second stage, values compiled from Rudnick and Gao (2003), and depleted mantle
176
Lu/
177
Lu = 0.0379, and
176
Hf/
177
Hf =
0.283164.
(f)
Apparent U-Pb age determined by LA-ICP-MS.
335